Ultrahigh piezoelectric coefficients of Li-doped (K,Na)NbO3 nanorod arrays with manipulated O-T phase boundary: Towards energy harvesting and self-powered human movement monitoring

نویسندگان

چکیده

Lead-free piezoelectric one-dimensional (1D) nanostructures have exhibited great potential in building biocompatible micro/nano-energy harvesters and self-powered smart sensors. However, their low coefficient still remains as the biggest obstacle for practical applications. In this work, an ultrahigh with calibrated d 33 from 400 pm V -1 to 814 is achieved Li-doped (K,Na)NbO 3 (KNLN) lead-free nanorod arrays (NRAs). The giant enhancement on performance of KNLN nanorods can be attributed manipulation phase transition behavior together relaxation strain. Li + dopants induce large NbO 6 octahedral distortion result decreased temperature orthorhombic (O) tetragonal (T) phase, which leads construction O-T boundary at room improves polarization products. NRAs gives rise remarkably improved energy harvesting performance, shows highly sensitive pressure sensing behaviors utilized monitoring human-body motions. Giant up (K,Na,Li)NbO by manipulating orthorhombic-tetragonal through A-site Li-doping. exhibit outstanding performances realize human body motions analyzing movement behaviors. • were grown hydrothermal process. ~ − 1 arrays. Orthorhombic-tetragonal constructed RT. nanogenerators performance. Self-powered human-body-movements realized nanogenerators.

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ژورنال

عنوان ژورنال: Nano Energy

سال: 2021

ISSN: ['2211-3282', '2211-2855']

DOI: https://doi.org/10.1016/j.nanoen.2021.106072